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Soil acidification in the tropics has become a more pressing issue due to its associated aluminum (Al) phytotoxicity. The chemically reactive nature of biochar can alter Al speciation in soils. The study assessed the chemical properties and Al speciation in an Ultisol and an Oxisol amended with corn cob (CC) and rice husk (RH) biochars charred at 300, 450 and 650°C in an incubation study for 120 d. pH was determined periodically while organic carbon (OC), cation exchange capacity (CEC), exchangeable base cations, exchangeable acidity, and exchangeable Al 3+ exchangeable acidity, soluble Al and Al were measured at the end of the incubation period. Dissolved organic carbon (DOC) and pH were also determined in soil solution from each treatment. Throughout the incubation period, CC and RH biochars significantly increased soil pH, with CC biochar showing a greater effect. Similar effects were also observed for OC, CEC, and exchangeable base cations (Ca 2+, Mg2+ and K+). Soil exchangeable Al3+ and activity in soil solution decreased significantly upon biochar application; it was more significant at 650°C. Biochars at 300–450°C exhibited a more notable increase in soil DOC. At pH ≤ 5.8, Al-DOC and free Al3+ dominated in soil solution while at pH > 5.8, Al species was mainly Al-OH ions (i.e. Al(OH)2+, Al(OH)+2, Al(OH)3- ). Biochars at 300–450°C promoted the large formation of Al-DOC while Al-OH ions dominated in 650°C-biochar treatments. Biochar can be used to ameliorate Al phytotoxicity in tropical acid soils, particularly at 300–450°C.